Every phase is a band of the sun’s angle. The sky beside each one is how it looks, and the name is what it means, so nothing depends on telling colors apart.
Daylightabove 35°The sun is high. Light is flat and top-down, shadows are short and hard. Outside the Lightphase working window.
35° Window6° to 35°Still low enough to be directional, but with fuller color and more contrast than golden hour. The long, workable middle of the day at either end.
Golden Hourthe horizon to 6°Warm, low, strongly directional sunlight. Long shadows, raking side light, and the shallowest angle direct sun ever reaches.
Civil Twilight−6° to the horizonBright twilight. Enough ambient light to expose a scene handheld, with no direct sun and almost no shadow.
Nautical Twilight−12° to −6°Deep blue sky. Silhouettes read cleanly against a faintly visible horizon. The window most people mean by "blue hour".
Astronomical Twilight−18° to −12°The darkest twilight. Stars remain prominent and the sky reads as black to the eye, but the horizon is beginning to separate on a long exposure.
Nightbelow −18°The sun is far enough below the horizon that it contributes no usable light. Full dark for photographic purposes.